M. Zielińska-Błajet

Dr.  MARIOLA ZIELIŃSKA-BŁAJET

Room: 233/ A-2,
Tel
: +480713202128
e-mail
: mariola.zielinska-blajet@pwr.wroc.pl

Education:
1988 – M.Sc. degree, Wrocław University of Technology (Prof. B. Karabon)
1995 – PhD. degree, Wrocław University of Technology (Prof. B. Bujnowska)
1997 – research associate at the Department of Organic Chemistry, Faculty of Chemistry, Wrocław University of Technology

Fellowships:
NIRE, Tsukuba, Japonia, 1996-1997, STA Postdoc (Dr Y. Yamada)

 

Research interests:

Synthesis of chiral heteroorganic compounds; their application for asymmetric catalysis, structural modifications of Cinchona alkaloids.

 

Selected publications:

1.  Zielińska-Błajet M., Skarżewski J. “Enantioselective Henry reaction catalyzed by copper(II)−Cinchona alkaloids complexes,” Tetrahedron: Asymmetry, 2011, 22, 351-355.

2. Wojaczyńska E., Zielińska-Błajet M., Turowska-Tyrk I., Skarżewski J. “Sulfoxides derived from Cinchona alkaloids – chiral ligands in palladium-catalyzed asymmetric allylic alkylation“, Tetrahedron: Asymmetry, 2010, 21, 853-858.

3. Zielińska-Błajet M., Skarżewski J. “New chiral thiols and C2-symmetrical disulfides of Cinchona alkaloids: ligands for the asymmetric Henry reaction catalyzed by CuII complexes“, Tetrahedron: Asymmetry, 2009, 20, 1992-1998.

4.  Zielińska-Błajet M., Siedlecka R., Skarżewski J. “Chiral phenylselenyl derivatives of pyrrolidyne and Cinchona alkaloids: nitrogen-selenium  donating ligands in palladium-catalyzed asymmetric allylic alkylation“, Tetrahedron: Asymmetry, 2007, 18, 131-136.

5.  Zielińska-Błajet M., Kucharska M., Skarżewski J.”Simple enantiospecific synthesis of sulfides of Cinchona alkaloids”, Synthesis 2006, 7,  1176-1182.

6.  Zielińska-Błajet M., Kowalczyk R., Skarżewski J. “Ring-closure reactions through intramolecular substitution of thiophenoxide by oxygen and nitrogen nucleophiles: simple stereospecific synthesis of 4,5-dihydroisoxazoles and 4,5-dihydropyrazoles”, Tetrahedron 2005, 61, 5253-5249.

7. Skarżewski J., Zielińska-Błajet M., Roszak S., Turowska-Tyrk I.”Cyclization of 1,3-diaryl-3-phenylsulfanyl-1-propanols to thiochromans with the participation of [1,3]-PhS shift”, Tetrahedron  2003, 59, 3621-3626.

8.  J. Skarżewski, R. Siedlecka, E. Wojaczyńska, M. Zielińska-Błajet “A new and  efficient route to homochiral g-hydroxysulfoxides and g-hydroxysulfones“, Tetrahedron: Asymmetry, 2002, 13, 2105-2111.   

9.  Skarżewski J., Zielińska-Błajet M., Turowska-Tyrk I. “Simple preparation of enantiomeric Michael adducts of thiophenol to chalcones: easily available new chiral building blocks”, Tetrahedron: Asymmetry, 2001, 12, 1923-1928.

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